Why can you stand on a glacier but not the ocean?
The answer seems simple enough: Liquids flow. Solids don’t. The atoms in liquids can slosh around. In solids, they fall lockstep into a crystal lattice. A crystal’s endlessly repeating pattern is so stable that it takes a considerable infusion of energy to make the atoms break rank. Or so physics textbooks say.
But this long-accepted explanation for the rigidity of solids fails to account for quasicrystals — bizarre solids first discovered in the lab in 1982 and found in nature in 2009. Atoms in quasicrystals are arranged in patterns that never repeat, but the material is nonetheless rigid. So is glass, an amorphous mass of stationary atoms that behaves like a solid but, upon closer inspection, looks more like a liquid frozen in time.
“Glasses have been around for thousands of years,” said Daniel Stein, a professor of physics and mathematics at New York University. “Chemists understand them. Engineers understand them. From the point of view of physics, we don’t understand them. Why are they rigid?”
Even crystalline solids such as glaciers resist categorization, as their atoms can flow, albeit very slowly. And sometimes the reverse also seems true: The ocean feels rigid if you jump onto it from a tall enough glacier. What, then, is the difference between a liquid and a solid?
Physicists in France and the United States are proposing new answers to this fundamental question. As outlined in a March article in the Notices of the American Mathematical Society, the researchers have identified two characteristics of materials that dramatically change form at the intersections of temperature and pressure where liquids turn solid. These characteristics, the physicists say, could define the difference between the two states of matter.
Charles Radin, a mathematical physicist at the University of Texas at Austin, and his former student, David Aristoff, now a mathematician at the University of Minnesota, argue that the main difference between liquids and solids is the way they respond to shear, or twisting forces. Liquids barely resist shear and can easily be sloshed, whereas solids — regardless of whether they are crystals, quasicrystals or glass — resist attempts to change their shape.
The liquid-solid phase transition, Radin and Aristoff reason, should therefore be marked by the “shear response” of a material jumping from zero to a positive value. And they observed just such a jump for a two-dimensional model material, in which atoms are represented by disks: At low densities corresponding to the material’s liquid phase, it showed no response to shear, but when the disks were densely packed, like the atoms in a solid, shear caused the material to expand. “The crossover where it shows this effect is exactly the density where the system becomes crystalline,” Radin said. “We propose this as a different way of understanding what a solid is.”